Star-Shaped Conjugated Systems

Star-Shaped Conjugated Systems

The present review deals with the preparation and the properties of star-shaped conjugated compounds. Three, four or six conjugated arms are attached to crossconjugated cores, which consist of single atoms (B, C, N), benzene or azine rings or polycyclic ring systems, as for example triphenylene or tristriazolotriazine. Many of these shape-persistent [n]star compounds tend to -stacking and self...

Large-Size Star-Shaped Conjugated (Fused) Triphthalocyaninehexaazatriphenylene.

Star-shaped triphthalocyaninehexaazatriphenylene 1 was synthesized via condensation between a new building block 1,2-diaminophthalocyanine and cyclohexanehexaone. Compound 1 represents the largest star-shaped phthalocyanine-fused hexaazatriphenylene reported so far. This largely expanded phthalocyanine shows good solubility and has a strong tendency to aggregate both in solution and on the surf...

Synthesis and properties of novel star-shaped oligofluorene conjugated systems with BODIPY cores

Star-shaped conjugated systems with varying oligofluorene arm length and substitution patterns of the central BODIPY core have been synthesised, leading to two families of compounds, T-B1-T-B4 and Y-B1-Y-B4, with T- and Y-shaped motifs, respectively. Thermal stability, cyclic voltammetry, absorption and photoluminescence spectroscopy of each member of these two families were studied in order to...

Star-Shaped and L-Shaped Orthogonal Drawings

An orthogonal drawing of a plane graph G is a planar drawing of G, denoted by D(G), such that each vertex of G is drawn as a point on the plane, and each edge of G is drawn as a sequence of horizontal and vertical line segments with no crossings. An orthogonal polygon P is called orthogonally convex if the intersection of any horizontal or vertical line L and P is either a single line segment o...

Convexifying star-shaped polygons